Priyamani married Mustafa Raj in 2017 in an intimate ceremony. Nearly four years later, there is trouble in their marriage. Mustafa's ex-wife Ayesha alleged that Priyamani's marriage with Mustafa is invalid. She claimed that Mustafa did not divorce her and hence his marriage with Priyamani doesn't count. Several hours after these allegations, Priyamani spoke to Bollywood Hungama to promote her film Narappa, which is the Telugu remake of Tamil film Asuran starring Dhanush. In her interview, Priyamani said that her relationship with Mustafa is very secure.
Speaking about their relationship, Priyamani said, "Communication is the key. If you’re asking about the relationship between me and Mustafa, by far, we are definitely very secure in our relationship, even though right now, he is in the US. He’s working there. We make it a point that we talk to each other every day. If he’s busy with work, he’ll probably call me or text me once he’s free. Or vice versa, if I’m busy with shooting, I would do that.” Priyamani also added that Mustafa is currently in the US while she is in India. However, they are secure as they put in the effort to ask about how they are doing and their day.